Geology, mineralization, sulfur isotope and fluid inclusion studies in alteration zones in Cu-Au-Mo south of Zahedan porphyry prospect (SE Iran)

Document Type : Reply to comment on Paper

Authors

Faculty of Earth Sciences, Shahid Beheshti University, Tehran, Iran

10.22059/ijmge.2023.353613.595020

Abstract

The study area is located 12 km south of Zahedan city in Sistan-Baluchestan province. This area includes the northern part of Sistan and Baluchestan province, which has a similar geological history as the Chagai belt beyond the Iranian border in Pakistan. The porphyry prospect south of Zahedan is located in the fertile belt of the Sistan suture zone, which includes the Janja, Siastragi, Chahuk and Kuh-e-Lar mineral structures, then leading to the Sindak Pakistan Molybdenum Porphyry Mine. Based on the results of the geological mapping of 1: 5,000 areas, a series of subvolcanic masses with intermediate chemical composition (related to the Zahedan granitoid) have been intruded into the sedimentary host rocks with flysch facies. The zoning of alteration occurrence in the region are concentric and with the center of phyllic and potassic alteration. Pyrite is the most abundant sulfide and chalcopyrite the main copper ore mineral. Mo and Cu mineralization in this area mainly occurred as veinlets in stockwork and dissemination texture. Based on scanning electron microscopy (SEM) studies and using EDS analysis, the presence of molybdenite, copper sulfide minerals were detected along with electrum and gold inclusions in the collected samples. Most of the detected fluid inclusions in study area are of the two, three, and multiphase types, including liquid, vapor, and solid. Due to the trend of salinity changes versus homogenization temperature, the effective fluid densities in the mineralization systems of the region are between 0.8 and more than 1.2 gr / cm3. Based on the salinity percentage (30 to 60 wt% NaCl equivalent) and homogenization temperature (200 to 500°C), the fluid inclusions of the region are in the porphyry range. Fluid δ34S values in the study samples are in the range of 3.4 to 4.6 per thousand. Sulfur isotope analyses indicate a magmatic origin of hydrothermal fluid. In general, based on the geology, mineralization, fluid inclusion, and sulfur stable Isotope studies it can be proposed that probably south Zahedan area is a copper, gold and molybdenum-type porphyry deposit.

Keywords

Main Subjects


[1] Abbas Etemadi, Mohammad Karimpour., 2022, Geological constraints on magmatic evolution in subduction zones and cumulative factors effective on the fertility of Cenozoic host porphyritic rocks associated with major porphyry copper deposits in the Lut Block and Kerman porphyry copper belt, Iran, Journal of Asian Earth Sciences. 7, p. 132-145.
[2] Aghazadeh, M., Hou, Z., Badrzadeh, Z. and Zhou, L., 2015, Temporal-Spatial Distribution and Tectonic Setting of Porphyry Copper Deposits in Iran: Constraints from Zircon U-Pb and Molybdenite Re-Os Geochronology. Ore Geology Reviews, 70, p. 385-406.
[3] Arthurton, R.S., Farah, A., and Ahmed, W., 1982, The Late Cretaceous-Cenozoic history of western Baluchistan Pakistan—the northern margin of the Makran subduction complex: Geological Society of London Special Publication. 10, p. 373–386.
[4] Bakker, R.J., 2011, Fluid Inclusions, Critical Review, Applications, Computer Modeling. Short Course. University of Leoben, Leoben.
[5] Bodnar, R.J., Lecumberri, S, P., Moncada, D., Steele-MacInnis, M., 2014, Fluid Inclusions in Hydrothermal Ore Deposits. In Turekian, H.D.H.K., Ed., Treatise on Geochemistry, 2nd Edition, Elsevier, Oxford, 5, p. 119-142.
[6] Bodnar, R.J., 1993, Revised equation and table for determining the freezing point depression of H2O–NaCl solutions. Geochim. Cosmochim. Acta 57, p. 683–684.
[7] Boomeri, M., Moradi, R., Stein, H., Bagheri, S., 2019, Geology, Re-Os age, S and O isotopic composition of the Lar porphyry Cu-Mo deposit, southeast Iran. Ore Geology Reviews, p. 104,
[8] Cannell, J., Cooke, D., Walshe, J., Stein, H., 2005. Geology, mineralization, alteration, and structural evolution of the El Teniente porphyry Cu–Mo deposit, Economic Geology, 100, p. 979–1003.
[9] Carrillo- Rosúa, J., Boyce, A. J., Morales-Ruano, S., Morata, D., Roberts, S., Munizaga, F., Moreno-Rodríguez, V., 2014, Extremely negative and inhomogeneous sulfur isotope signatures in Cretaceous Chilean manto- type Cu– (Ag) deposits, Coastal Range of central Chile, Ore Geology Reviews 56, 3, p.13–24.
[10] Christos L., Stergiou, Vasilios Melfos, Panagiotis Voudouris, Paul G. Spry, 2020, The Geology, Geochemistry, and Origin of the Porphyry Cu-Au-(Mo) System at Vathi, Serbo-Macedonian Massif, Greece,
[11] Doebrich, J, L., Wahl, R, R., 2007, Geologic and mineral resource map of Afghanistan: U.S. Geological Survey Open-File Report 2006-1038, scale 1:850,000.
[12] Eastoe, C, J., 1978, A Fluid Inclusion Study of the Panguna Porphyry Copper Deposit, Bougainville, Papua New Guinea. Economic Geology, 73, p. 721-748.
[13] Fournier, R, O., 1999, Hydrothermal processes related to movement of fluid from plastic into a brittle rock in the magmatic-epithermal environment. Economic Geology 94, p. 1193–1212.
[14] Guilbert, J, M., Park, C, F., 1986, The Geology of Ore Deposits. W. H. Freeman and Company, New York.
[15] Gustafson, L, B., Hunt, J, P., 1975, The porphyry copper deposit at El Salvador, Chile: Economic Geology, 70, p. 857–912.
[16] Hedenquist, J, W., Lowenstern, J, B., 1994, The role of magmas in the formation of hydrothermal ore deposits, Nature, 370, p. 519–527.
[17] Heinrich, C, A., Kouzmanov, K., von Quadt, A., Peytcheva, I., Harris, C, R., 2007, Miocene magmatism and ore formation in the south Apuseni Mountains, Romania: New genetic and timing constraints, Irish Association for Economic Geology, 1, p. 865–868.
[18] Henley, R, W., Berger, B, R., 2013, Nature’s refineries–metals and metalloids in arc volcanoes. Earth Science Reviews, 125, p. 146-170.
[19] Henley, R, W., Ellis A, J., 1983, Geothermal systems ancient and modern, a geochemical review. Earth-Sci. Rev., 19, p. 1–50.
[20] Hunt, J, P., Bratt, J, A., Marquardt, J, C., 1983, Quebrada Blanca, Chile: An enriched porphyry copper deposit, Mining Engineering, 35, p. 636−644.
[21] Hunting Survey Corporation Ltd., 1960, Reconnaissance geology of part of west Pakistan: A Colombo Plan Cooperative Project, Toronto, Report by Government of Canada for Government of Pakistan, 550 p.
[22] Kojima, S., Trista-Aguilera, D., Hayashi, K., 2008, Genetic Aspects of the Manto-type Copper Deposits Based on Geochemical Studies of North Chilean Deposits. Resource Geology 59, 4, p. 87–98.
[23] Large, R, R., Bull, S, W., Cooke, D, R., McGoldrick, P, J., 1998, A Genetic Model for the HYC Deposit, Australia, Based on Regional Sedimentology, Geochemistry and Sulfide-Sediment Relationship. Economic Geology, 93, p. 1345-1368.
[24] Lawrence, R, D., Khan, S, H., DeJong, K, A., Farah, A., Yeats, R, S., 1981, Thrust and strike-slip fault interaction along the Chaman transform zone, Pakistan, Geological Society [London] Special Publication 9, p. 363–370.
[25] Martin Ramos, J, D., 2004, XPowder, a software package for powder X‐ray diffraction analysis. Legal Deposit GR 1001/04.
[26] Meyer, C., Hemley, J, J, 1967, Wall rock alteration, in Geochemistry of Hydrothermal Ore Deposits (ed. H.L. Barnes). New York, Holt, Rinehart, and Winston, p. 166–235.
[27] Moghadam, H, S., Stern, R, J., 2015, Ophiolites of Iran: Keys to understanding the tectonic evolution of SW Asia :(II) Mesozoic ophiolites. J., Asian. Earth. 100, p. 31- 59.
[28] Nicholson, K, N., Khan, M., Mahmood, K., 2010, Geochemistry of the Chagai-Raskoh arc, Pakistan: Complex arc dynamics spanning the Cretaceous to the Quaternary, Lithos, 118, p. 338–348.
[29] Ohmoto, H., Rye, R, O., 1997, Isotopes of sulfur and carbon. In Geochemistry of hydrothermal ore deposits, Ed, Barnes, H. L., Wiley- Interscience, New York. p 509- 567.
[30] Ohmoto, H., 1972, Systematics of sulfur and carbon isotopes in hydrothermal ore deposits. Economic Geology,67, 3, p. 551–579.
[31] Pearlyn Manalo, a, b., Ryohei Takahashi, a., Akira Imai, C., Rhyza, R., 2022, Heterogeneity of mineral chemistry and sulfur isotopic composition of alunite in the Mankayan lithograph, northern Luzon, Philippines, 146, p. 104- 159.
[32] Perello, J., Razique, A., Schloderer, J., Asad-ur-Rehman., 2008, The Chagai porphyry copper belt, Baluchistan province, Pakistan, Economic Geology, 103, p. 1583–1612.
[33] Richards, J, P., and Sholeh, A., 2016, The Tethyan tectonic history and Cu-Au metallogeny of Iran: Society of Economic Geologists Special Publication, 19, p. 193–212.
[34] Richards, J, P., 2011, Magmatic to Hydrothermal Metal Fluxes in Convergent and Collided Margins. Ore Geology Reviews, 40, p. 1-26.
[35] Roedder, E., 1992, Fluid Inclusion Evidence for Immiscibilility in Magmatic Differentiation. Geochimica et Cosmochimica Acta, 56, p 5- 20.
[36] Roedder. E., 1984, Fluid inclusions. Reviews in Mineralogy 12, 644 pp.
[37] Rollinson, H, R., 1993, Using Geochemical Data: Evaluation, Presentation, and Interpretation. Longman Scientific and Technical, New York.
[38] Sadeghian. M., 2004, Ph.D. Thesis in Geology, Petrology, University of Tehran., Magmatism, metallurgy and mechanism of granitoid mass replacement in Zahedan.
[39] Samson, I., Anderson, A., Marshall, D, D., 2003, Fluid Inclusions, Analysis and Interpretation. Mineralogical Association of Canada.
[40] Shafiei, B., Haschke, M., Shahabpour, J., 2009, Recycling of Orogenic Arc Crust Triggers Porphyry Cu Mineralization in Kerman Cenozoic Arc Rocks, Southeastern Iran. Mineralium Deposita, 44, p. 265-283.
[41] Seedorf, E., Dilles, J, H., Proffett, J, M., Einaudi, M, T., Zurcher, L., Stavast, W, J, A., Johnson, D, A., Barton, M, D., 2005, Porphyry Deposits: Characteristics and Origin of Hypogene Features. Economic Geology 100th Anniversary, p. 251-298.
[42] Shepherd, T, J., Rankin, A, H., Alderton, D, H, M., 1985, A Practical Guide to Fluid Inclusion Studies. Blackie Press, London.
[43] Sheppard, D, H., 1971, Competition between two chipmunk species (Eutamias). Ecology, 52, p. 320–329.
[44] Selby, D., Feely, M., Costanzo, A. and Li, X, H., 2016, Fluid Inclusion Characteristics and Molybdenite Re-Os Geochronology of the Qulong Porphyry Copper-Molybdenum Deposit, Tibet. Mineralium Deposita, 51, p. 1-22.
[45] Siddiqui, R, H., 2004, Crustal evolution of Chagai-Raskoh arc terrane, Balochistan, Pakistan: Ph.D. thesis, Peshawar, Pakistan, University of Peshawar, 353 p.
[46] Sillitoe, R, H., 2010, Porphyry Copper Systems. Economic Geology, 105, p. 3-41.
[47] Sillitoe, R, H., 1978, Metallogenic evolution of a collisional mountain belt in Pakistan a preliminary analysis, Journal of the Geological Society London, 135, p. 377–387.
[48] Sillitoe, R, H., Khan, S, N., 1977, Geology of the Saindak porphyry copper deposit, Pakistan Transactions of the Institution of Mining and Metallurgy, 86, B27–B42.
[49] Sillitoe, R, H., 1972, Relation of metal provinces in western America to subduction of oceanic lithosphere: Geological Society of America Bulletin, 83, p. 813–818.
[50] Soleymani, M., Niroomand, S., Rajabi, A., Monecke, T., and Modabberi, S., 2021, Metallogeny of the Zahedan-Nehbandan magmatic belt and implications to porphyry Cu exploration in southeastern Iran, EGU General Assembly, online, p. 19–30.
[51] SmichaelSterner, D, HallRobert, J, B., 1988, Synthetic fluid inclusions. V. Solubility relations in the system NaCl-KCl-H2O under vapor-saturated conditions, Geochimica et Cosmochimica Acta, 52, 5, p. 989-1005.
[52] Takenouchi, S., 1980, Preliminary Studies on Fluid Inclusions of the Santo Tomas II (Philex) and Tapian (Marcroper) Porphyry Copper Deposits in the Philippines. Mining Geology Special.
[53] Tirrul, R, I, R., Bell, R, J., Griffis, V. E., 1983, The Sistan suture zone of eastern Iran, Geol. Soc. Am. Bull., 94, p. 134 – 150.
[54] Vasilios, M., Panagiotis, V., Margarita, M., Matías, G. S., 2020, Mineralogical Constraints on the Potassic and Sodic-Calcic Hydrothermal Alteration and Vein-Type Mineralization of the Maronia Porphyry Cu-Mo ± Re ± Au Deposit in NE Greece.
[55] Wilkinson, J, J., 2001, Fluid Inclusions in Hydrothermal Ore Deposits. Lithos, 55, p. 229-272.
[56] Wilson, A, J., 2003, The geology, genesis and exploration context of the Cadia gold-copper porphyry deposits, NSW, Australia: Ph.D. thesis, Hobart, University of Tasmania, 335 p.
[57] Whitney, D, L., Evans, B, W., 2010, Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 1, p. 185–187.
[58] X'Pert HighScore Plus, 2004, Version 2. 2d, PANalytical BV.
[59] Yi Cao A., Zejun Zheng, B., Yilun Du, A, C., Fuping Gao, A., Xinlong, Q., 2017, Ore geology and fluid inclusions of the Hucunnan deposit, Tongling, Eastern China: Implications for the separation of copper and molybdenum in skarn deposits, Volume 81, Part 2, p. 925-939.
[60] Zahid, H., T., Chun-Feng, L., Shili, L., 2021, Mineralogy, Fluid Inclusions, and Isotopic Study of the Kargah Cu-Pb Polymetallic Vein-Type Deposit, Kohistan Island Arc, Northern Pakistan Implication for Ore Genesis, Minerals, 11, p. 1266.